1. komponenta

Lecture type	Total
Lectures	30
Seminar	15

* Load is given in academic hour (1 academic hour = 45 minutes)

Electrolyte solutions: strong electrolyte structural models (Debye&Hückel, Bjerrum, Fuoss); weak electrolytes, polyelectrolytes. Galvanic cell: electrical interfacial layer, electromotivity (electromotive force) ? definition and measurements; ion-selective electrodes; potentiometry and potentiometric titration. Kinetics of electrode reactions: polarization, overpotential; Butler-Volmer model, Tafel plot; electrodes: dropping mercury electrode, stationary electrodes, rotating electrodes. Voltammetric methods: polarography, stationary voltammetry, linear sweep voltammetry, cyclic voltammetry, square vawe voltammetry, anodic stripping voltammetry, adsorptive stripping voltammetry, electrochemical impedance spectroscopy. Applications: electrochemical analysis, fuel cells, corrosion, bioelectrochemistry.
Learning outcomes:
After passing the exam student should be able to:
1. Describe and explain the properties of electrolyte solutions
2. Describe and compare the structural models of strong electrolyte solutions (Debye&Hückel, Bjerrum, etc)
3. Explain the application of glass electrode for measuring pH.
4. Name the basic voltammetric techniques and explain their most important properties and applications.
5. Describe and explain the kinetics of electrode processes using Butler-Volmer model.
6. Explain the application of electrochemistry on the example of electrochemical analysis, fuel cells, corrosion and bioelectrochemistry.

1. A. J. Bard, L. R. Faulkner: Electrochemical Methods, Wiley, New York, 2001.
2. J. Wang: Analytical Electrochemistry, Wiley, New York, 2000.
3. J. O'M. Bockris, A. K. N. Reddy, Modern Electrochemistry, Vol. 1, 2. izd., Kluwer Academic/Plenum Press, New York, 2002.
4. K. B. Oldham, Fundamentals of Electrochemical Science, Academic Press, Inc., San Diego, 1994.
5. P. W. Atkins, J. de Paula: Atkins' Physical Chemistry, 9. izd., Oxford Univ. Press, Oxford, 2010.
6. I. Piljac: Senzori fizikalnih veličina i elektroanalitičke metode, Media Print, Zagreb, 2010.
7. I. Piljac: Elektroanalitičke metode, RMC, Zagreb, 1995.
8. Vl. Simeon: Equilibria in Electrolyte Solutions, u: N. Kallay (ur.), Interfacial Dynamics, M. Dekker, New York, 2000.

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Izborni predmeti izvan odabranih grana - Regular study - Inorganic and organic chemistry
Izborni predmeti fizikalna kemija - Regular study - Inorganic and physical chemistry
Izborni predmeti izvan odabranih grana - Regular study - Inorganic chemistry and biochemistry
Izborni predmeti fizikalna kemija - Regular study - Physical and organic chemistry

Izborni predmeti izvan odabranih grana - Regular study - Analytical and inorganic chemistry
Izborni predmeti izvan odabranih grana - Regular study - Analytical and organic chemistry
Izborni predmeti fizikalna kemija - Regular study - Analytical and physical chemistry
Izborni predmeti izvan odabranih grana - Regular study - Analytical chemistry and biochemistry
Izborni predmeti izvan odabranih grana - Regular study - Biochemistry and organic chemistry
Izborni predmeti fizikalna kemija - Regular study - Biochemistry and physical chemistry
Izborni predmeti izvan odabranih grana - Regular study - Inorganic and organic chemistry
Izborni predmeti fizikalna kemija - Regular study - Inorganic and physical chemistry
Izborni predmeti izvan odabranih grana - Regular study - Inorganic chemistry and biochemistry
Izborni predmeti fizikalna kemija - Regular study - Physical and organic chemistry