Theoretical Phenomenological Thermodynamics: Mathematical and physical background (Pfaff forms , homogeneous functions, Jacobians, characteristic functions). Axiomatics (principle of Carathéodory). Relativistic generalisation. Theoretical Statistical Thermodynamics: Theory of probability. Principles of quantum mechanics. Stationary model (the method of ensembles). Classical approximation, the partition function method. The evaluation of the stationary model, density matrix. Fluctuations. The method of molecular partition function. Models based on canonical ensemble: Debye model of crystal, real gases, electrolyte solutions (P. Debye i E. Hückel, J. E. Mayer, Monte Carlo methods and molecular dynamics). Irreversible processes: Generalised fluxes and forces, linear phenomenological relations (Onsager). Nonlinear phenomena (dissipative structures, oscillating chemical reactions). Thermochemistry: Thermometry. Calorimetry. Standard thermodynamic properties. Tables of thermodynamic properties.
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- OBVEZNA LITERATURA:
E. A. Guggenheim: Thermodynamics, 5. izd. North-Holland, Amsterdam 1967.
H. Margenau, G. M. Murphy: The Mathematics of Physics and Chemistry, Vol. I, Van Nostrand, New York 1956. (pogl. 1, 11, 12), Vol. II, Van Nostrand, New York 1964. (pogl. 8).
M. L. McGlashan: Chemical Thermodynamics, Academic Press, London 1979.
G. Nicolis, I. Prigogine: Self_organization in Non_equilibrium Systems, Wiley, New York 1977; (ruski prijevod: Samoorganizacija v neravnovesnyh sistemah, Mir, Moskva 1979).
Vl. Simeon: Termodinamika, Školska knjiga, Zagreb 1980.
J. R. Waldram: The Theory of Thermodynamics, Cambridge University Press, Cambridge 1985.
J. O. M. Bockris, A. K. N. Reddy: Modern Electrochemistry, 2. izd., Vol. 1, Plenum Press, New York 1998.
- DOPUNSKA LITERATURA:
revijalni članci i znanstvene monografije
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